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MICHIGAN STATE UNIVERSITY
College of Natural Science
Department of Chemistry

Publications

  1. “Synthesis and Structure-Activity Relationships of Novel Arylfluoroquinolone Antibacterial Agents” Chu, D. T. W.; Fernandes, P. B.; Claiborne, A. K.; Pihuleac, E.; Nordeen, C. W.; Maleczka, R. E., Jr.; Pernet, A. G. J. Med. Chem. 1985, 28, 1558–1564. (pdf)
  2. “Synthesis and Structure-Activity Relationship of 1-Aryl-6,8-difluoroquinolone Antibacterial Agents” Chu, D. T. W.; Fernandes, P. B.; Maleczka, R. E., Jr.; Nordeen, C. W.; Pernet, A. G. J. Med. Chem. 1987, 30, 504–509. (pdf)
  3. “Synthesis of 4-Oxo-4H-quino[2,3,4-i,j][1,4]-benoxazine-5-carboxylic Acid Derivatives” Chu, D. T. W.; Maleczka, R. E., Jr. J. Heterocyclic Chem. 1987, 24, 453–456. (pdf)
  4. “Total Synthesis of Didemnins A, B, and C” Rinehart, K. L.; Kishore, V.; Nagarajan, S.; Lake, R. J.; Gloer, J. B.; Bozich, F. A.; Li, K.-M.; Maleczka, R. E., Jr.; Todsen, T. L.; Munro, M. H. G.; Sullins, D. W.; Sakai, R. J. Am. Chem. Soc. 1987, 109, 6846–6848. (pdf)
  5. “Synthesis of 4,12-Dihydro-4-oxoquino-[1,8a,8-a,b]quinoxaline-5-carboxylic Acid Derivatives” Chu, D. T. W.; Maleczka, R. E., Jr.; Nordeen, C. W. J. Heterocyclic Chem. 1988, 25, 927–930. (pdf)
  6. “Enantioselective Total Synthesis of (–)-9-Epiambrox, a Potent Ambergris-Type Olfactory Agent” Paquette, L. A.; Maleczka, R. E., Jr. J. Org. Chem. 1991, 56, 912–913. (pdf)
  7. “Regio- and Stereoselective Oxidation of Unsaturated Bicyclo[2.2.2]octanones with Selenium Dioxide” Paquette, L. A.; Maleczka, R. E., Jr.; Qiu, F.-y. J. Org. Chem. 1991, 56, 2455–2461. (pdf)
  8. “Adaptation of Oxyanionic Sigmatropy to the Convergent Enantioselective Synthesis of Ambergris-Type Odorants” Maleczka, R. E., Jr.; Paquette, L. A. J. Org. Chem. 1991, 56, 6538–6546. (pdf)
  9.  “Enantioselective Construction of Natural (+)-Pallescensin A.  A Sigmatropic Pathway to Furanosequeterpines” Paquette, L. A.; Maleczka, R. E., Jr. J. Org. Chem. 1992, 57, 7118–7122. (pdf)
  10. “Rapamycin Synthetic Studies.  1. Construction of the C(27) to C(42) Subunit” Smith, A. B., III; Condon, S. M.; McCauley, J. A.; Leahy, J. W.; Leazer, J. L., Jr.; Maleczka, R. E., Jr. Tetrahedron Lett. 1994, 35, 4907–4910. (pdf)
  11. “Rapamycin Synthetic Studies.  2. Construction of the C(10) to C(26) Perimeter” Smith, A. B., III; Maleczka, R. E., Jr.; Leazer, J. L., Jr.; Leahy, J. W.; McCauley, J. A.; Condon, S. M. Tetrahedron Lett. 1994, 35, 4911–4914. (pdf)
  12. “Total Synthesis of Rapamycin and Demethoxyrapamycin” Smith, A. B., III; Condon, S. M.; McCauley, J. A.; Leazer, J. L., Jr.; Leahy, J. W.; Maleczka, R. E., Jr. J. Am. Chem. Soc. 1995, 117, 5407–5408. (pdf)
  13. “A Unified Total Synthesis of the Immunomodulators (–)-Rapamycin and (–)-27-Demethoxyrapamycin:  Construction of the C(21–42) Perimeters” Smith, A. B., III; Condon, S. M.; McCauley, J. A.; Leazer, J. L., Jr.; Leahy, J. W.; Maleczka, R. E., Jr. J. Am. Chem. Soc. 1997, 119, 947–961. (pdf)
  14. “A Unified Total Synthesis of the Immunomodulators (–)-Rapamycin and (–)-27-Demethoxyrapamycin:  Assembly of the Common C(1–20) Perimeter and Final Elaboration” Smith, A. B., III; Condon, S. M.; McCauley, J. A.; Leazer, J. L., Jr.; Leahy, J. W.; Maleczka, R. E., Jr. J. Am. Chem. Soc. 1997, 119, 962–973. (pdf)
  15. “Stereospecificity of the 1,2-Wittig Rearrangement:  How Chelation Effects Influence Stereochemical Outcome” Maleczka, R. E., Jr.; Geng, F. J. Am. Chem. Soc. 1998, 120, 8551–8552. (pdf)
  16. “Development of a One Pot Palladium Catalyzed Hydrostannylation/Stille Coupling Protocol with Catalytic Amounts of Tin” Maleczka, R. E., Jr.; Terstiege, I. J. Org. Chem. 1998, 63, 9622–9623. (pdf)
  17. “A New Approach for the Generation and Reaction of Organotin Hydrides:  The Development of Reactions Catalytic in Tin” Terstiege, I.; Maleczka, R. E., Jr. J. Org. Chem. 1999, 64, 342–343. (pdf)
  18. “Application of a Three-Carbon Ring Expansion Process to Bridged Bicyclic Systems” Mi, B.; Maleczka, R. E., Jr. Tetrahedron Lett. 1999, 40, 2053–2056. (pdf)
  19. “Synthetic Studies Toward Amphidinolide A: Synthesis of Fully Functionalized Subunits” Terrell, L. R.; Ward, J. S., III; Maleczka, R. E., Jr. Tetrahedron Lett. 1999,40, 3097–3100. (pdf)
  20. “Synthesis of Aryl and Alkyl Acylsilanes Using Trimethyl(tributylstannyl)silane” Geng, F.; Maleczka, R. E., Jr. Tetrahedron Lett. 1999,40, 3113–3114. (pdf)
  21. "Application of Fluoride Catalyzed Silane Reductions of Tin Halides to the in situPreparation of Vinylstannanes” Maleczka, R. E., Jr.; Terrell, L. R.; Clark, D. H.; Whitehead, S. L.; Gallagher, W. P.; Terstiege, I. J. Org. Chem. 1999, 64, 5958–5965. (pdf)
  22. “Synthesis and Fluoride Promoted Wittig Rearrangements of alpha-Alkoxysilanes” Maleczka, R. E., Jr.; Geng, F. Org. Lett. 1999, 1, 1111–1113. (pdf)
  23. “Methyllithium Promoted Wittig Rearrangements of alpha-Alkoxysilanes” Maleczka, R. E., Jr.; Geng, F. Org. Lett. 1999, 1, 1115–1118. (pdf)
  24. “Stille Couplings Catalytic in Tin — Beyond Proof of Principle” Maleczka, R. E., Jr.; Gallagher, W. P.; Terstiege, I. J. Am. Chem. Soc. 2000, 122, 384–385. (pdf)
  25. “Microwave Assisted One Pot Hydrostannylation/Stille Couplings” Maleczka, R. E., Jr.; Lavis, J. M.; Clark, D. H.; Gallagher, W. P. Org. Lett. 2000, 2, 3655–3658. (pdf)
  26. “Stille Couplings Catalytic in Tin — The 'Sn–O' Approach” Gallagher, W. P.; Terstiege, I.; Maleczka, R. E., Jr. J. Am. Chem. Soc. 2001, 123, 3194–3204. (pdf)
  27. “A Nozaki-Hiyama-Kishi (NHK) Coupling Approach to the Phomactins” Mi, B.; Maleczka, R. E., Jr. Org. Lett. 2001, 3, 1491–1494. (pdf)
  28. “The Regiochemical Influence of Oxo-Substitution in Palladium Mediated Hydrostannations of 1-Alkynes” Rice, M. B.; Whitehead, S. L.; Horvath, C. M.; Muchnij, J. A.; Maleczka, R. E., Jr.Synthesis 2001, 1495–1504. (pdf)
  29. “Stille Couplings Catalytic in Tin: A “Sn–F” Approach” Maleczka, R. E., Jr.;Gallagher, W. P. Org. Lett. 2001, 3, 4173–4176. (pdf)
  30. “Remarkably Selective Iridium Catalysts for the Elaboration of Aromatic C–H Bonds” Cho, J.-Y.; Tse, M. K.; Holmes, D.; Maleczka, R. E., Jr.; Smith, M. R., III Science 2002, 295, 305–308. (pdf)
  31. “Total Synthesis of Proposed Amphidinolide A via a Highly Selective Ring Closing Metathesis” Maleczka, R. E., Jr.;Terrell, L. R.; Geng, F.; Ward, J. S., III Org. Lett. 2002, 4, 2841–2844.  (pdf)
  32. “Palladium Catalyzed Hydrodehalogenations by Fluoride Activated Polymethylhydro-siloxane” Maleczka, R. E., Jr.;Rahaim, R. J., Jr.; Teixeira, R. R. Tetrahedron Lett. 2002, 43, 7087–7090. (pdf)
  33. “Bleach/Acetic Acid Promoted Chlorinative Ring Expansion of [2.2.1] and [2.2.2] Bicycles” Ruggles, E. L.; Maleczka, R. E., Jr. Org. Lett. 2002, 4, 3899–3902. (pdf)
  34. “Room Temperature Dehalogenation of Chloroarenes by Polymethylhydrosiloxane (PMHS) under Palladium Catalysis” Rahaim, R. J., Jr.; Maleczka, R. E., Jr. Tetrahedron Lett. 2002, 43, 8823–8826. (pdf)
  35. “Polymethylhydrosiloxane (PMHS) as an Additive in Sonogashira Reactions” Gallagher, W. P.; Maleczka, R. E., Jr. Synlett 2003, 537–541. (pdf)
  36. “C–H Activation/Borylation/Oxidation:  A One-Pot Unified Route To Meta-Substituted Phenols Bearing Ortho/Para-Directing Groups” Maleczka, R. E., Jr.; Shi, F.; Holmes, D.; Smith, M. R., III J. Am. Chem. Soc. 2003, 125, 7792–7793. (pdf)
  37. “PMHS Mediated Couplings of Alkynes or Benzothiazoles with Various Electrophiles: Application to the Synthesis of (–)-Akolactone A” Gallagher, W. P.; Maleczka, R. E., Jr. J. Org. Chem. 2003, 68, 6775–6779. (pdf)
  38. “Stille Reactions Catalytic in Tin: A “Sn-F” Route for Intermolecular and Intramolecular Couplings” Gallagher, W. P.; Maleczka, R. E., Jr. J. Org. Chem. 2005, 70, 841–846. (pdf)
  39. “A Toxicological Evaluation of Pyrene Ozonation Byproducts: Biphenyl-2,2',6,6'-tetracarb-aldehyde and Biphenyl-2,2',6,6'-tetracarboxylic Acid” Luster-Teasley, S. L.; Ganey, P. E.; DiOrio, M.; Ward, J. S., III; Maleczka, R. E., Jr.; Trosko, J. E.; Masten, S. J. Environ. Toxicol. Chem. 2005, 24, 733–740. (pdf)
  40. “Pd-Catalyzed Silicon Hydride Reductions of Aromatic and Aliphatic Nitro Groups” Rahaim, R. J., Jr.; Maleczka, R. E., Jr. Org. Lett. 2005, 7, 5087–5090. (pdf)
  41. “One-Pot Pd-Catalyzed Hydrostannation/Stille Reaction with Acid Chlorides as the Electrophiles” Lee, K.; Gallagher, W. P.; Toskey, E. A.; Chong, W.; Maleczka, R. E., Jr. J. Organomet. Chem. 2006, 691, 1462–1465. (pdf)
  42. “One-Pot Borylation/Amination Reactions: Synthesis of Arylamine Boronate Esters from Halogenated Arenes” Holmes, D.; Chotana, G. A.; Maleczka, R. E., Jr.; Smith, M. R., III Org. Lett. 2006, 8, 1407–1410. (pdf)
  43. “Aromatic Borylation/Amidation/Oxidation: A Rapid Route to 5-Substituted-3-amidophenols” Shi, F.; Smith, M. R., III; Maleczka, R. E., Jr. Org. Lett. 2006, 8, 1411–1414. (pdf)
  44. “Pd(0)-Catalyzed PMHS Reductions of Aromatic Acid Chlorides to Aldehydes” Lee, K.; Maleczka, R. E., Jr. Org. Lett. 2006, 8, 1887–1888. (pdf)
  45. “-Substituted Acylsilanes via a Highly Selective [1,4]-Wittig Rearrangement of α-Benzyloxyallylsilane” Onyeozili, E. N.; Maleczka, R. E., Jr. Chem. Commun. 2006, 2466–2468. (pdf)
  46. “Studies on the Deprotonation and Subsequent [1,4]-Wittig Rearrangement of α-Benzyloxyallylsilanes” Onyeozili, E. N.; Maleczka, R. E., Jr.Tetrahedron Lett. 2006, 47, 6565–6568. (pdf)
  47. “Pd-Catalyzed Silane/Siloxane Reductions in the One-Pot Conversion of Nitro Compounds to Their Amines, Hydroxylamines, Amides, Sulfonamides, and Carbamates” Rahaim, R. J., Jr.; Maleczka, R. E., Jr. Synthesis 2006, 3316–3340. (pdf)
  48. “Ir-Catalyzed Functionalization of 2-Substituted Indoles at the 7-Position: Nitrogen-Directed Aromatic Borylation” Paul, S.; Chotana, G. A.; Holmes, D.; Reichle, R. C.; Maleczka, R. E., Jr.; Smith, M. R., III J. Am. Chem. Soc. 2006, 128, 15552–15553. (pdf)
  49. “Iridium-Catalyzed Borylation of Thiophenes: Versatile, Synthetic Elaboration Founded on Selective C–H Functionalization” Chotana, G. A.; Kallepalli, V. A.; Maleczka, R. E., Jr.; Smith, M. R., III Tetrahedron 2008, 64, 6103–6114. (pdf)
  50. “Aryl–Aryl Cross-Couplings that Avoid the Preparation of Haloaromatics” Norberg, A. M.; Sanchez, L.; Maleczka, R. E., Jr. Curr. Opin. Drug Discov. Dev. 2008, 11, 853–869. (pdf)
  51. “Copper Puts Arenes in a Hard Position (A Chemistry Perspective)” Maleczka, R. E., Jr. Science 2009, 323, 1572–1573. (pdf)
  52. “Reactions of vinyltributylgermanes and aryl halides under Heck conditions” Torres, N. M.; Lavis, J. M.; Maleczka, R. E., Jr.Tetrahedron Lett. 2009, 50, 4407–4410. (pdf)
  53. “Getting the Sterics Just Right: A Five-Coordinate Iridium Trisboryl Complex that Reacts with C—H Bonds at Room Temperature” Chotana, G. A.; Vanchura, B. A., II; Tse, M. K.; Staples, R. J.; Maleczka, R. E., Jr.; Smith, M. R., III Chem. Commun. 2009, 5731–5733. (pdf)
  54. “Boc Groups as Protectors and Directors for Ir-Catalyzed C–H Borylation of Heterocycles” Kallepalli, V. A.; Shi, F.; Paul, S.; Onyeozili, E. N.; Maleczka, R. E., Jr.; Smith, M. R., III J. Org. Chem. 2009, 74, 9199–9201. (pdf)
  55. “Divergent Synthesis of 2,3,5-Substituted Thiophenes by C–H Activation/Borylation/Suzuki Coupling" Kallepalli, V. A.; Sanchez, L.; Li, H.; Gesmundo, N. J.; Turton, C. L.; Maleczka, R. E., Jr.; Smith, M. R., III Heterocycles 2010, 80, 1429–1448. (pdf)
  56. “Enzymatic Kinetic Resolution of a-Hydroxysilanes” An, I.; Onyeozili, E. N.; Maleczka, R. E., Jr. Tetrahedron: Asymmetry 2010, 21, 527–534. (pdf)
  57. “Electronic Effects in Iridium C–H Borylations: Insights From Unencumbered Substrates and Variation of Boryl Ligand Substituents” Vanchura, B. A., II; Preshlock, S. M.; Roosen, P. C. Kallepalli, V. A.; Staples, R. J.; Maleczka, R. E., Jr.; Singleton, D. A.; Smith, M. R., III Chem. Commun. 2010, 46, 7724–7726. (pdf)
  58. “C–O Hydrogenolysis Catalyzed by Pd-PMHS Nanoparticles in the Company of Chloroarenes” Rahaim, R. J., Jr.; Maleczka, R. E., Jr. Org. Lett. 2011, 13, 584–587. (pdf)
  59. “Practical One-Pot C–H Activation/Borylation/Oxidation: Preparation of 3-Bromo-5-Methylphenol on a Multi-Gram Scale” Staples, R. J.; Smith, M. R., III; Maleczka, R. E., Jr. Synthesis 2011, 857–859. (pdf)
  60. “Ni, Co, & Mo-metal-catalyzed alkynes hydrostannations using Bu3SnCl/PMHS/KF/18-crown-6 as an in situ Bu3SnH source” Ghosh, B.; Maleczka, R. E., Jr. Tetrahedron Lett. 2011, 52, 5285–5287. (pdf)
  61. “Outer-Sphere Direction in Iridium C–H Borylation” Roosen, P. C.; Kallepalli, V. A.; Chattopadhyay, B.; Maleczka, R. E., Jr.; Singleton, D. A; Smith, M. R., III J. Am. Chem. Soc. 2012, 134, 11350–11353. (pdf)
  62. “[1,2]- and [1,4]-Wittig Rearrangements of α-Alkoxysilanes: Effect of Substitutions at both the Migrating Benzylic Carbon and the Terminal sp2 Carbon of the Allyl Moiety” Onyeozili, E. N.; Mori-Quiroz, L. M.; Maleczka, R. E., Jr. Tetrahedron 2013, 69, 849–860. (pdf)
  63. “Non-Pd Transition Metal Catalyzed Hydrostannations: Bu3SnF/PMHS as a Tin Hydride Source” Ghosh, B.; Maleczka, R. E., Jr. Tetrahedron 2013, 69, 4000–4008. (pdf)
  64. “High Throughput Optimization of Ir-Catalyzed C–H Borylation: A Tutorial for Practical Applications” Preshlock, S. M.; Ghaffari, B.; Maligres, P. E.; Krska, S. W.; Maleczka, Robert E.; Jr.; Smith, M. R., III J. Am. Chem. Soc. 2013, 135, 7572–7582. (pdf)
  65. “A Traceless Directing Group for C–H Borylation” Preshlock, S. M.; Plattner, D. L.; Maligres, P. E.; Krska, S. W.; Maleczka, R. E.; Jr.; Smith, M. R., III Angew. Chem. Int. Ed. 2013, 42, 12915–12919. (pdf)
  66. “A One-Pot Allylation-Hydrostannation Sequence with Recycling of the Intermediate Tin Waste” Ghosh, B.; Amado-Sierra, M. R. I.; Holmes, D.; Maleczka, R. E.; Jr. Org. Lett. 2014, 16, 2318–2321. (pdf)
  67. “Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis” Ghaffari, B.; Preshlock, S. M.; Plattner, D. L.; Staples, R. J.; Maligres, P. E.; Krska, S. W.; Maleczka, R. E.; Jr.; Smith, M. R., III J. Am. Chem. Soc. 2014, 136, 14345–14348. (pdf)
  68. “A Catalytic Borylation / Dehalogenation Route to ortho-Fluoro Arylboronates” Jayasundara, C. R. K.; Unold, J. M.; Smith, M. R., III; Maleczka, R. E.; Jr. Org. Lett. 2014, 16, 6072–6075. (pdf)
  69. “Stereoconvergent [1,2]- and [1,4]-Wittig Rearrangements of 2-Silyl-6-aryl-5,6-dihydropyrans: A Tale of Steric vs. Electronic Regiocontrol of Divergent Pathways” Mori-Quiroz, L. M.; Maleczka, R. E., Jr. J. Org. Chem. 2015, 80, 1163–1191. (pdf).
  70. “Harnessing C–H Borylation/Deborylation for Selective Deuteration, Synthesis of Boronate Esters, and Late Stage Functionalization” Kallepalli, V. A.; Gore, K. A.; Shi, F.; Sanchez, L.; Chotana, G. A.; Miller, S. L.; Maleczka, R. E., Jr.; Smith, M. R., III J. Org. Chem. 2015, 80, 8341–8353. (pdf)
  71. “Reversible Borylene Formation from Ring-Opening of Pinacolborane and Other Intermediates Generated From 5-Coordinate Trisboryl Complexes: Implications for Catalytic C–H Borylation” Ghaffari, B.; Vanchura, B. A., II; Chotana, G. A.; Staples, R. J.; Holmes, D.; Maleczka, R. E., Jr.; Smith, M. R., III Organometallics 2015, 34, 4732–4740. (pdf)
  72. “Bismuth Acetate as a Catalysts for the Sequential Protodeboronation of Di- and Triborylated Indoles” Shen, F.; Tyagarajan, S.; Perera, D.; Krska, S. W.; Maligres, P. E.;  Smith, M. R., III; Maleczka, R. E., Jr. Org. Lett. 2016, 18, 1554–1557. (pdf)
  73. “Improved Synthesis of Electron Deficient Bipyridines” Li, H.; Oppenheimer, J.;  Smith, M. R., III; Maleczka, R. E., Jr. Tetrahedron Lett. 2016, 57, 2231–2232. (pdf)
  74. “Ir-Catalyzed ortho-Borylation of Phenols Directed by Substrate-Ligand Electrostatic Interactions: A Combined Experimental / in Silico Strategy for Optimizing Weak Interactions” Chattopadhyay, B.; Dannatt, J. E.; Andujar-De Sanctis, I. L.; Gore, K. A.; Maleczka, R. E.; Jr.; Singleton, D. A.; Smith, M. R., III J. Am. Chem. Soc. 2017, 139, 7864–7871. (pdf)
  75. “Achieving High Ortho Selectivity in Aniline C-H Borylations by Modifying Boron Substituents” Smith, M. R., III; Bisht, R.; Haldar, C.; Pandey, G.; Dannatt, J. E.; Ghaffari, B.; Maleczka, R. E.; Jr.; Chattopadhyay, B. ACS Catal. 2018, 8, 6216–6223. (pdf)
  76. “Cobalt-Catalyzed C-H Borylation of Alkyl Arenes and Heteroarenes Including the First Selective Borylations of Secondary Benzylic C–H Bonds” Jayasundara, C. R. K.; Sabasovs, D.; Staples, R. J.; Oppenheimer, J.; Smith, M. R., III; Maleczka, R. E., Jr. Organometallics 2018,37, 1567–1574. (pdf)
  77. “Separation of Asymmetrically Capped Double-Decker Silsesquioxanes Mixtures” Vogelsang, D. F.; Dannatt, J. E.; Maleczka, R. E., Jr.; Lee, A. Polyhedron 2018, 155, 189–193. (pdf)
  78. “HPLC Characterization of cis and trans Mixtures of Double-Decker Shaped Silsesquioxanes” Vogelsang, D. F.; Maleczka, R. E., Jr.; Lee, A. Silicon 2019, 11, 5–13. (pdf)
  79. “Predictive Liquid Chromatography Separation for Mixtures of Functionalized Double-decker Shaped Silsesquioxanes Based on HPLC Chromatograms” Vogelsang, D. F.; Maleczka, R. E., Jr.; Lee, A. Ind. Eng. Chem. Res. 2019, 58, 403–410. (pdf)
  80. “Phase Behavior of cis–transMixtures of Double-Decker Shaped Silsesquioxanes for Processability Enhancement” Vogelsang, D. F.; Dannatt, J. E.; Shoen, B. W.; Maleczka, R. E., Jr.; Lee, A. ACS Appl. Nano Mater. 2019, 2, 1223–1231. (pdf)
  81. “A General Diversity Oriented Synthesis of Asymmetric Double-Decker Shaped Silsesquioxanes” Barry, B.-D.; Dannatt, J. E.; King, A. K.; Lee, A.; Maleczka, R. E., Jr. Chem. Commun.2019, 55, 8623–8626. (pdf)
  82. “C–H Borylation Catalysts that Distinguish Between Similarly Sized Substituents Like Fluorine and Hydrogen” Miller, S. L.; Chotana, G. A.; Fritz, J. A.; Chattopadhyay, B.; Maleczka, R. E., Jr.; Smith, M. R., III Org. Lett. 2019, 21, 6388–6392. (pdf)
  83. “Para-Selective, Iridium-Catalyzed C–H Borylations of Sulfated Phenols, Benzyl Alcohols, and Anilines Directed by Ion-Pair Electrostatic Interactions” Montero Bastidas, J. R.; Oleskey, T. J.; Miller, S. L.; Smith, M. R., III; Maleczka, R. E., Jr. J. Am. Chem. Soc. 2019, 141, 15483–15487. (pdf)
  84. “One-Pot Iridium-Catalyzed C–H Borylation / Sonogashira Cross-Coupling: Access to Borylated Aryl Alkynes” Chotana, G. A.; Montero Bastidas, J. R.; Miller, S. L.; Smith, M. R., III; Maleczka, R. E., Jr. Molecules 2020, 25, 1754–1766. (pdf)
  85. “Silylcyclopropanes by Selective [1,4]-Wittig Rearrangement of 4-Silyl-5,6-dihydropyrans” Mori-Quiroz, L. M.; Maloba, E. W.; Maleczka, R. E., Jr. Org. Lett. 2021, 23, 5724–5728. (pdf)
  86. “Phase behavior of selected condensed double-decker shaped silsesquioxane compounds” Vogelsang, D. F.; Maleczka, R. E., Jr.; Lee, A. Silicon. 2021, 14, 7555–7565. (pdf)
  87. “Amide Directed Iridium C(sp3)–H Borylation Catalysis with High N-Methyl Selectivity” Dannatt, J. E.; Yadav, A.; Smith, M. R., III; Maleczka, R. E.; Jr. Tetrahedron 2022, 109, 132578. (pdf)
  88. “Merging Iridium-Catalyzed C–H Borylations with Palladium-Catalyzed Cross-Couplings using Triorganoindium Reagents” Jayasundara, C. R. K.; Gil-Negrete, J.-M.; Montero Bastidas, J. R.; Martínez, M. M.; Sestelo, J. P.; Smith, M. R., III; Maleczka, R. E.; Jr. J. Org. Chem. 2022, 86, 751–759. (pdf)
  89. “Steric shielding effects induced by intramolecular C–H•••O hydrogen bonding: remote borylation directed by Bpin groups” Montero Bastidas, J. R.; Chhabra, A.; Feng, Y.; Oleskey, T. J.; Smith, M. R., III; Maleczka, R. E.; Jr. ACS Catal. 2022, 12, 2694–2705. (pdf)
  90. “Regiochemical Switching in Ir-Catalyzed C–H Borylation by Altering Ligand Loadings of N,B-Type Diboron Species” O’Connell, A. C.; Mansour, P. A.; Maleczka, R. E., Jr.; Smith, M. R., III Org. Lett. 2023, 25, 8057–8061. (pdf)
  91. “Access to C(sp3) Borylated and Silylated Cyclic Molecules: Hydrogenation of Corresponding Arenes and Heteroarenes” Chhabra, A.; Reich, S.; Shannon, T. M.; Ghaffari, B.; Maleczka, R. E., Jr.; Smith, M. R., III RSC Advances 2024, 14, 10590–10607. (pdf)
  92. “Simple and Green Preparation of Tetraalkoxydiborons and Diboron Diolates from Tetrahydroxydiboron” Fornwald, R. M.; Yadav, A.; Montero Bastidas, J. R.; Smith, M. R., III; Maleczka, R. E., Jr. J. Org. Chem. 2024, 89, 6048–6052. (pdf)
  93. “Iridium-Catalyzed Anti-Markovnikov Hydrosilylation of Vinylbenzenes with a Bis-Silane-Capped Double-Decker Silsesquioxane” Walsh, S. P.; Lee, A.; Maleczka, R. E., Jr. Organometallics 2024, 43, 1085–1094. (pdf)
  94. “A Hydrazone Ligand for Iridium-Catalyzed C–H Borylation: Enhanced Reactivity and Selectivity for Fluorinated Arenes” Peruzzi, C. D.; Miller, S. L.; Dannatt, J. E.; Maleczka, R. E., Jr.; Smith, M. R., III Organometallics 2024, 43, 1208–1212. (pdf)
  95. “On the Inconsistencies in Previously Reported Protections of the Catechol Moiety of L-DOPA” Yang, C.; Fan, J.; Maleczka, R. E., Jr. Tetrahedron. Lett. 2024, 144, 155150. (pdf)
  96. “Balancing Reactivity, Regioselectivity and Product Stability in Ir-catalyzed Ortho C–H Borylations of Anilines by Modulating the Diboron Partner” Montero Bastidas, J. R.; Yadav, A.; Lee, S.; Ghaffari, B.; Smith, M. R., III; Maleczka, R. E., Jr. Org. Lett. 2024, 26, 5420–5424. (pdf)

Book Chapters

  1. “Advances in the Total Synthesis of Amphidinolide A” Maleczka, R. E., Jr.; Terrell, L. R. In Natural Product Chemistry at the Turn of the Century; Rahman, A.-u.; Choudhary, M. I.; Khan, K. M., Eds.; Print Arts: Karachi 2002; pp. 105–114.
  2. “Polymethylhydrosiloxane (PMHS)” Lavis, J. M.; Maleczka, R. E., Jr. In eEROS–Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Wipf, P., Eds.; Wiley: New York; Published online April 15, 2003, http://onlinelibrary.wiley.com/o/eros/articles/rn00062/frame.html. (pdf)
  3. “(R)-(–)-2,2-Diphenylcyclopentanol” Onyeozili, E. N.; Maleczka, R. E., Jr. In eEROS– Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Wipf, P., Eds.; Wiley: New York, Published online April 15, 2003, http://onlinelibrary.wiley.com/o/eros/articles/rn00225/frame.html. (pdf)
  4. “(4S,5S)-2-Bromo-1,3-bis[(4-methylphenylsulfonyl]-4,5-diphenyl-1,3,2-diazaborolidine” Pellerito, A. M.; Maleczka, R. E., Jr. In eEROS–Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Wipf, P., Eds.; Wiley: New York, Published online October 15, 2003,
    http://onlinelibrary.wiley.com/o/eros/articles/rn00224u/frame.html. (pdf)
  5. “Triethylsilane (First Update)” Rahaim, R. J., Jr.; Maleczka, R. E., Jr. In eEROS–Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Molander, G. A., Eds.; Wiley: New York; Published online March 17, 2007, http://onlinelibrary.wiley.com/o/eros/articles/rt226/frame.html. (pdf)
  6. “Triphenylsilane (First Update)” Torres, N. M.; Maleczka, R. E., Jr. In eEROS–Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Molander, G. A., Eds.; Wiley: New York; Published online March 17, 2007, http://onlinelibrary.wiley.com/o/eros/articles/rt385/frame.html. (pdf)
  7. “Trimethylene Oxide (First Update)” Muchnij, J. A.; Maleczka, R. E., Jr. In eEROS– Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Molander, G. A., Eds.; Wiley: New York; Published online September 17, 2007, http://onlinelibrary.wiley.com/o/eros/articles/rt273/frame.html. (pdf)
  8. “Bismuth Pentafluoride” Kim S.-H.; Maleczka, R. E., Jr. In eEROS–Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Molander, G. A., Eds.; Wiley: New York; Published online September 17, 2007, http://onlinelibrary.wiley.com/o/eros/articles/rn00735/frame.html. (pdf)
  9. “1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate) (First Update)” An, I.; Maleczka, R. E., Jr. In eEROS–Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Molander, G. A., Eds.; Wiley: New York; Published online September 17, 2007,
    http://onlinelibrary.wiley.com/o/eros/articles/rc116/frame.html. (pdf)
  10. “Chlorotrimethylstannane (First Update)” Lee, K.; Maleczka, R. E., Jr. In eEROS–Electronic Encyclopedia of Reagents for Organic Synthesis (DOI: 10.1002/047084289X); Paquette, L. A.; Crich, D.; Fuchs, P. L.; Molander, G. A., Eds.; Wiley: New York; Published online September 17, 2007, http://onlinelibrary.wiley.com/o/eros/articles/rc160/frame.html. (pdf)
  11. “Catalytic Hydrodehalogenation Reactions” Ghosh, B.; Maleczka, R. E., Jr. In Science of Synthesis: Catalytic Reduction in Organic Synthesis Vol. 1 (DOI 10.1055/b-005-145236); de Vries, J. G., Ed.; Georg Thieme Verlag KG: Stuttgart 2018; pp. 355–373.

Patents

  1. “Processes and Intermediates for Preparing Macrocycles” Smith, A. B., III; Condon, S. M.; Leahy, J. W.; Leazer, J. L., Jr.; Maleczka, R. E., Jr.; McCauley, J. A. U.S. Patent 5,621,108; April 15, 1997. (pdf)
  2. “Process for the Synthesis of Phenols from Arenes” Maleczka, R. E., Jr.; Smith, M. R., III; Holmes, D.; Shi, F. U.S. Patent 6,828,466; December 7, 2004. (pdf)
  3. “Process for the Catalytic Synthesis of Biaryls and Polymers from Aryl Compounds” Smith, M. R., III; Maleczka, R. E., Jr. U.S. Patent 6,867,302; March 15, 2005. (pdf)
  4. “Synthesis of Aminoboronic Esters and Substituted Anilines from Arenes via Catalytic C–H Activation/Borylation/Amination and Uses Thereof” Maleczka, R. E., Jr.; Smith, M. R., III; Holmes, D. U.S. Patent 6,958,196; October 25, 2005. (pdf)
  5. “Process for the Catalytic Synthesis of Biaryls and Polymers from Aryl Compounds” Smith, M. R., III; Maleczka, R. E., Jr. U.S. Patent 7,148,356; December 12, 2006. (pdf)
  6. “Process for the Preparation of a Borylated Thiophene”  Smith, M. R., III; Maleczka, R. E., Jr.; Chotana, G. A.; Kallepalli, V.; Paul, S. U.S. Patent Application 2008-0091035; April 17, 2008. (pdf)
  7. “Process for Producing N-Protected Boryl Compounds” Smith, M. R., III; Maleczka, R. E., Jr.; Kallepalli, V.; Onyeozili, E. U.S. Patent Application 2008-0146814; June 19, 2008. (pdf)
  8. “Process for the Preparation of 2-Substituted-7-Boryl Indoles and Compounds” Smith, M. R., III; Maleczka, R. E., Jr.; Chotana, G. A.; Paul, S. U.S. Patent Application 2008-0167476; July 10, 2008. (pdf)
  9. “Process for Producing Cyano Substituted Arene Boranes and Compounds” Smith, M. R., III; Maleczka, R. E., Jr.; Chotana, G. A. U.S. Patent 7,514,563; April 7, 2009. (pdf)
  10. “Process for Producing Oxazole, Imidazole, Pyrrazole Boryl Compounds” Smith, M. R., III; Maleczka, R. E., Jr.; Kallepalli, V.; Onyeozili, E. U.S. Patent 7,709,654; May 4, 2010. (pdf)
  11. “Methods for Producing Borylated Arenes” Smith, M. R., III; Maleczka, R. E., Jr.; Li, H.; Jayasundara, C.; Oppenheimer, J.; Sabasovs, D. U.S. Patent Application No. 20150065743; March 5, 2015. (pdf)
  12. “Methods for Producing Borylated Arenes” Smith, M. R., III; Maleczka, R. E., Jr.; Sabasovs, D.; Oppenheimer, J. U.S. Patent Application 20150361109; December 17, 2015. (pdf)
  13. “Synthetic Methods for Forming Saturated (Hetero)cyclic Borylated Hydrocarbons and Related Compounds” Smith, M. R., III; Shannon, T. M.; Maleczka, R. E., Jr.; Fornwald, R. M. U.S. Patent Application 20180051042; February 22, 2018. (pdf)
  14. “Synthetic Methods for Diboron Reagents and Related Compounds Arenes” Smith, M. R., III; Maleczka, R. E., Jr. U.S. Patent 10,077,278; September 18, 2018.
  15. “Methods for Producing Borylated Arenes” Smith, M. R.; Maleczka, R. E.; Li, H.; Jayasundara, C. R. K.; Oppenheimer, J.; Sabasovs, D. U.S. Patent 10,112,960; October 30, 2018.
  16. “Methods for Producing Borylated Arenes” Smith, M. R., III; Maleczka, R. E., Jr.; Sabasovs, D.; Oppenheimer, J. U.S. Patent 10,166,533; January 1, 2019.
  17. “Methods for Producing Borylated Arenes” Smith, M. R.; Maleczka, R. E.; Li, H.; Jayasundara, C. R. K.; Oppenheimer, J.; Sabasovs, D. U.S. Patent Application 201900620350; February 28, 2019.